[Answer] In which Bond movie did 007’s Aston Martin make its first appearance?

Step 1 : Introduction to the question "In which Bond movie did 007’s Aston Martin make its first appearance?"

...1. "Dr. No" 2. "Goldfinger" 3. "Live and Let Die" 4. "The Spy Who Loved Me"

Step 2 : Answer to the question "In which Bond movie did 007’s Aston Martin make its first appearance?"

"Goldfinger" - With its distinctively sleek styling, the Aston Martin is an iconic part of the James Bond series. Just as everyone knows how 007 likes his martini, so they know what he drives. Several different models have appeared throughout the series, usually bedecked with various hidden gadgets and weaponry. The first to make its mark on screen was the DB5 in the 1964 classic, "Goldfinger." The DB5 was also featured in "Thunderball," "Goldeneye," and "Skyfall.":

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